赣中新衡萤石矿床成矿流体特征研究：来自流体包裹体及氢氧同位素的证据     

张栋梁  吴德海  潘家永  吴赞华  陈光飞  欧阳斌  费磊  袁庚红  胡昊  余明军 《地质论评》2024,70(S1):70-72

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河嘉203H含硫水平气井测试工艺实践     

唐波  乔智国  陈伟  叶翠莲 《海洋地质译丛》2010,(4):103-105

河嘉203H井是川东北河坝构造嘉二高压含硫气藏部署的第一口水平井,具有埋藏深、储层压力高、腐蚀分压高、地层易漏失、水平井压井堵漏难度大的特点,通过开展工具优选、管柱结构优化设计、流程优选,并对替浆、放喷油嘴控制及压井等主要工序的施工工艺参数进行研究,形成了河坝嘉二含硫气藏水平井测试工艺技术体系,并在河嘉203H井获得成功应用。  相似文献   

Interaction of glucose and cellulose with hydrogen sulphide and polysulphides     

M.E.C. Moers  J.W. de Leeuw  H.C. Cox  P.A. Schenck 《Organic Geochemistry》1988,13(4-6)

This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor.  相似文献   

Responses of the tropospheric ozone and odd hydrogen radicals to column ozone change     

S. C. Liu  M. Trainer 《Journal of Atmospheric Chemistry》1988,6(3):221-233

The response of tropospheric ozone to a change in solar UV penetration due to perturbation on column ozone depends critically on the tropospheric NO _x (NO+NO₂) concentration. At high NO _x or a polluted area where there is net ozone production, a decrease in column ozone will increase the solar UV penetration to the troposphere and thus increase the tropospheric ozone concentration. However, the opposite will occur, for example, at a remote oceanic area where NO _x is so low that there is net ozone destruction. This finding may have important implication on the interpretation of the long term trend of tropospheric ozone. A change in column ozone will also induce change in tropospheric OH, HO₂, and H₂O₂ concentrations which are major oxidants in the troposphere. Thus, the oxidation capacity and, in turn, the abundances of many reduced gases will be perturbed. Our model calculations show that the change in OH, HO₂, and H₂O₂ concentrations are essentially independent of the NO _x concentration.  相似文献   

粤北新洲逆冲推覆断裂系统中断层岩的地球化学特征     

彭少梅 《岩石学报》1993,9(4):357-366

粤北新洲逆冲推覆断裂系统由Ⅰ，Ⅱ，Ⅲ－Ⅳ级推覆断层带组成，断层带中形成一套复杂的断层岩系，断层岩中Ａｕ，Ｐｂ，Ｗ，Ｓｂ，Ｂｉ，Ｈｇ，普遍富集，由此引起不同程度的金矿化，分别形成石英碳酸盐糜棱岩型金矿，碎裂钠长石岩型金矿和石英脉型金矿，成矿时期为印支晚期到燕山期，通过系统的微量元素，同位素和流体包裹体研究表明，１级推覆断层带断层岩中的成矿物质主要来自下地壳或上地幔，ＩＩ级推覆断层带断层岩中的成矿物质  相似文献   

Laboratory simulation of natural leaching processes of eastern USA oil shale     

M. Shirav  T. L. Robl 《Environmental Geology》1993,22(1):88-94

Raw and retorted spent oil shales from Kentucky, as well as soil and overburden materials, were subjected to laboratory and field leaching tests. Standard batch leaching tests grossly undervalue the amount of dissolved ions as measured in the field, being too brief to enable slow reactions of the mineral matrix, such as hydrolysis and oxidation of sulfides or reactions of acidic leachates with soluble components of the clays. Laboratory column tests, devised to closely simulate natural leaching processes, achieved concentration levels and elemental release patterns similar to those found in field tests. The column tests provide a reliable means to assess the leachability of metals in these materials.  相似文献   

电气石和水之间的氢同位素分馏   总被引：1，自引：0，他引：1  

钱雅倩  郭吉保 《地球学报》1994,15(Z1):189-196

作者对电气-水体系氢同位素平衡分馏和动力学分馏和动力学分馏开展了实验研究，丰富了羟基矿物氢同位素分馏资料。本文对该研究的实验技术、分析方法作了介绍，并对实验结果进行讨论与国外已有的该方面的资料作了对比。在800-650℃时电气石和水之间氢同位素平衡分馏系数与温度间线性关系为103lna电气石-水=-28.24（106/T2）+2.60；交换速率常数与温度间关系为lnk2=-0.19-6.70（103/T）  相似文献   

六合—仪征第三纪大陆碱性玄武岩微量元素地球化学     

支霞臣 《岩石学报》1990,6(2)

本文报道了六合-仪征第三纪大陆碱性玄武岩十八个样品的REE、Rb、Ba、Sr、Nb、Zr、Ni、Cr、V、Sc、Y、Ga、Zn、Cu等痕量元素含量,讨论了该岩套的成因及其地幔源区的特征。石榴石橄榄岩型地幔源区经较小程度部分熔融形成了基性原始岩浆;其后经过橄榄石和单斜辉石为主的结晶分异作用,演化后的岩浆喷出地表形成玄武岩套。本区碱性玄武岩的地幔源区曾受近期富集作用影响,具有富集LREE等不相容元素的特征。  相似文献   

宁南山区雹块氘含量的分析          下载免费PDF全文

杨颂禧  马伟  陈玉山 《大气科学》1991,15(3):24-30

由10个大雹块(长轴47—64mm)切片中的43个氘样分析得知:雹块的平均δD值为-93.8‰,其相应高度为海拔807m(-14.7℃),干生长层的平均δD值为-101.8‰,相应高度为8803m(-19.5℃),湿生长层的平均δD值为-91.5‰,相应高度为7413m(-11.4℃)。氘含量与冰晶平均长度之间有较好的统计关系。  相似文献   

The effect of gas-phase chemistry on aqueous-phase sulfur dioxide oxidation rates     

William R. Stockwell 《Journal of Atmospheric Chemistry》1994,19(3):317-329

The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO _x termination mechanism for the HO—SO₂ reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO₂ radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO₂ production from the HO—SO₂ reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates.  相似文献